The way I’m used to it is: 1. Wake up 2. Breakfast 3. Brush teeth.
Having it as 1, 3, 2 doesn’t make sense for me.
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You should wait about 30min after eating something acidic: https://www.cuimc.columbia.edu/news/brushing-immediately-after-meals-you-may-want-wait . Some people don’t have time to wait. Myself I don’t eat breakfast at home, I brush my teeth, go to work and eat when I arrive.
